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Unité de Formation et de Recherche de Chimie

" Development of radical based synthetic strategies for the total synthesis of natural products and Posttranslational modification of proteins Monday " 1st October 2018


Tandem cycloaddition reaction of allenyldiazao precursor vis via trimethylenemethane(TMM)-diyl was developed to contruct complex polycyclic structures in a single operation. This TMM-diyl cycloaddition reaction was successfully applied to the total synthesis of natural products with very challenging structural features. Radical based C-C bond forming reaction was developed for the study of posttranslational modification (PTM) and demonstrated to mimic Lys modification in PTM.


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