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Unité de Formation et de Recherche de Chimie

" Extracting mecanistic information in molecular electrochemistry " on Monday 13th 2019



  (emmanuel.maisonhaute @


"Extracting mecanistic information in molecular electrochemistry"

Abstract.  This presentation will aim at giving specific clues when ones wishes to lead an electrochemical mechanistic investigation for systems either reacting in solution or adsorbed onto the electrode. Starting from simple electron transfer reactions, we will next consider coupled chemical reactions. The frequently encountered square scheme mechanism will be particularly detailed. Finally, for macromolecules bearing several redox centers (dendrimers, rotaxanes), we will explain how the intramolecular electron hopping can be measured thanks to ultrafast cyclic voltammetry, and what can be deduced about molecular movements.



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