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Unité de Formation et de Recherche de Chimie

"Dipyrrin-based self-assembled architectures" Monday January 27th

Stéphane BAUDRON

CNRS-Université de Strasbourg UMR 7140 

sbaudron @ 

"Dipyrrin-based self-assembled architectures" 


Dipyrrins are bis-pyrrolic derivatives that can be rather easily synthesized and functionalized, forming monoanionic chelates under mild basic conditions. These features make them interesting ligands for the elaboration of discrete and infinite metal-organic architectures. In particular, our efforts have centered on the preparation of polynuclear helicates and Metal-Organic Frameworks using hydrogen or coordination bonding as well as Ag-π interactions. The construction strategies, the structural characteristics and the physical properties of these self-assembled systems will be presented. 



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